Nickel is a chemical element with the chemical symbol "Ni" and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel
belongs to the transition metals and is hard and ductile.
Pure nickel shows a significant chemical activity that can be observed when
nickel is powdered to
maximize the exposed surface area on which reactions can occur, but
larger pieces of the metal are slow to react with air at ambient conditions due
to the formation of a protective oxide surface. Even then, nickel is reactive
enough with oxygen so that native nickel is rarely found on Earth's
surface, being mostly confined to the interiors of larger nickel–iron
meteorites that were
protected from oxidation during their time in space. On Earth, such native
nickel is always found in combination with iron, a reflection of those
elements' origin as major end products of supernova nucleo synthesis. An iron–nickel
mixture is thought to compose Earth's inner core.
The use
of nickel (as a natural meteoric nickel–iron alloy) has been traced as
far back as 3500 BC. Nickel was first isolated and classified as a chemical
element in 1751 by Axel Fredrik Cronstedt, who initially
mistook its ore for a copper mineral. The element name
comes from a mischievous sprite of German miner's mythology, Nickel (similar to Old Nick), that personified the fact that
copper-nickel ores resisted refinement into copper. An economically important
source of nickel is the iron ore limonite, which often
contains 1-2% nickel. Nickel's other important ore minerals includegarnierite,
and pentlandite.
Major production sites include Sudbury region in Canada (which is thought to be of
meteoric origin), New Caledonia in the Pacific and Norilsk in Russia.
Because
of nickel's slow rate of oxidation at room temperature, it is considered
corrosion-resistant. Historically this has led to its use for plating metals such as iron and brass, to its use for
chemical apparatus, and its use in certain alloys that retain a high silvery polish,
such as German silver.
About 6% of world nickel production is still used for corrosion-resistant
pure-nickel plating. Nickel was once a common component of coins, but has
largely been replaced by cheaper iron for this purpose, especially since the
metal is a skin allergen for some people.
Nickel is
one of four elements that are ferromagnetic around room temperature. Alnico permanent magnets based partly on
nickel are of intermediate strength between iron-based permanent magnets and rare-earth
magnets. The metal is chiefly valuable in the modern world for the alloys it forms; about 60% of world
production is used in nickel-steels (particularly stainless steel).
Other common alloys, as well as some new super alloys,
make up most of the remainder of world nickel use, with chemical uses for
nickel compounds consuming less than 3% of production. As a compound, nickel has a number of
niche chemical manufacturing uses, such as a catalyst for
hydrogenation. Enzymes of some microorganisms and plants contain
nickel as an active site,
which makes the metal an essential nutrient for them.
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